New synthetic pathways to the preparation of near-blue emitting heteroleptic Ir( iii )N 6 coordinated compounds with microsecond lifetimes
A high yield synthetic route for the preparation of N 6 coordinated heteroleptic Ir( iii ) complexes using bidentate polypyridyl type ligands is described. The complexes are near-blue emitters and show microsecond emission lifetimes, high emission quantum yields and have two quasi-reversible reducti...
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Published in | Chemical communications (Cambridge, England) Vol. 50; no. 49; pp. 6461 - 6463 |
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Main Authors | , , , , , , , , , |
Format | Journal Article |
Language | English |
Published |
2014
|
Online Access | Get full text |
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Summary: | A high yield synthetic route for the preparation of N
6
coordinated heteroleptic Ir(
iii
) complexes using bidentate polypyridyl type ligands is described. The complexes are near-blue emitters and show microsecond emission lifetimes, high emission quantum yields and have two quasi-reversible reduction processes between −1.0 and −1.3 V
vs.
Ag/AgCl. |
---|---|
ISSN: | 1359-7345 1364-548X |
DOI: | 10.1039/C4CC02249A |