Manganese(III)-mediated alkenyl C-sp2-P bond formation from the reaction of beta-nitrostyrenes with dialkyl phosphites

Mn(OAc)(3)-mediated tandem phosphonyl radical addition to beta-nitrostyrenes followed by denitration to form (E)-2-alkenyl phosphonates in good yield is described.

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Bibliographic Details
Published inOrganic & biomolecular chemistry Vol. 13; no. 17; pp. 4896 - 4902
Main Authors Xue, Jian-Fei, Zhou, Shao-Fang, Liu, Ye-Ye, Pan, Xiangqiang, Zou, Jian-Ping, Asekun, Olayinka Taiwo
Format Journal Article
LanguageEnglish
Published CAMBRIDGE Royal Soc Chemistry 01.01.2015
Subjects
Chemistry
Chemistry, Organic
Physical Sciences
Science & Technology
ROUTE
CARBON
CATALYZED HYDROPHOSPHORYLATION
PHOSPHORYLATION
VERSATILE
FREE-RADICAL REACTIONS
TERMINAL ALKYNES
OXIDATIVE ADDITION
EFFICIENT
NITROALKENES
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Summary:Mn(OAc)(3)-mediated tandem phosphonyl radical addition to beta-nitrostyrenes followed by denitration to form (E)-2-alkenyl phosphonates in good yield is described.
ISSN:1477-0520
1477-0539
DOI:10.1039/c5ob00404g