Versatile techniques based on the Thermionic Vacuum Arc (TVA) and laser-induced TVA methods for Mg/Mg:X thin films deposition-A review

• Published in: Journal of magnesium and alloys Vol. 12; no. 8; pp. 3115 - 3134
• Main Authors: Vladoiu, R., Mandes, A., Dinca, V., Tichy, M., Kudrna, P., Ciobotaru, C.C., Polosan, S.
• Format: Journal Article
• Language: English
• Published: Elsevier B.V 01.08.2024; KeAi Communications Co., Ltd
• Subjects: Laser induced; Magnesium; Magnesium alloys; Thermionic vacuum arc; Thin films; Thin films; Thermionic vacuum arc; Laser induced; Magnesium; Magnesium alloys
• ISSN: 2213-9567; 2213-9567
• DOI: 10.1016/j.jma.2024.08.012

•Magnesium and magnesium alloys deposited by thermionic vacuum arc.•Amorphous thin film deposition with smooth surfaces.•Laser-induced method increases the crystallinity of the deposited thin films.•Both methods allow the alloying process with other materials as Ag, Zn, C.•The thermal energy during photonic processes increases the local temperature variation. Magnesium and magnesium thin alloy films were deposited using a thermionic vacuum arc (TVA), which has multiple applications in the field of metallic electrodes for diodes and batteries or active corrosion protection. An improved laser-induced TVA (LTVA) method favors the crystallization processes of the deposited magnesium-based films because the interaction between laser and plasma discharge changes the thermal energy during photonic processes due to the local temperature variation. Plasma diagnosis based on current discharge measurements suggests an inelastic collision between the laser beam and the atoms from the plasma discharge. The morphology and surface properties of the obtained thin films differ between these two methods. While the amorphous character is dominant for TVA thin films, enabling a smooth surface, the LTVA method produces rough surfaces with prominent crystallinity, less hydrophobic character and lower surface energy. The smooth surfaces obtained by the TVA methods produce metallic electrodes with good electrical contact, ensuring better diodes and battery charge transport. Both methods allow uniform magnesium alloys to be obtained, but the laser used in the LTVA on the discharge plasma controls the added metal or element ratio. [Display omitted]