Biomimetic one-step access to nitraramine from simple C-5 units. Revision of the previously reported structure of epinitraramine to nitraramine
A single biomimetic cascade sequence featuring intermolecular followed by intramolecular cyclizations allowed the biomimetic synthesis of nitraramine from simple C-5-lysine-derived metabolites. In the course of the study, the structure of epinitraramine was also revisited.
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Published in | Organic letters Vol. 7; no. 12; pp. 2497 - 2499 |
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Main Authors | , , |
Format | Journal Article |
Language | English |
Published |
WASHINGTON
Amer Chemical Soc
09.06.2005
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Subjects | |
Online Access | Get full text |
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Summary: | A single biomimetic cascade sequence featuring intermolecular followed by intramolecular cyclizations allowed the biomimetic synthesis of nitraramine from simple C-5-lysine-derived metabolites. In the course of the study, the structure of epinitraramine was also revisited. |
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ISSN: | 1523-7060 1523-7052 |
DOI: | 10.1021/ol050849q |