A new class of C-1-symmetric monosulfoximine ligands for enantioselective hetero Diels-Alder reactions

Quinoline-based C-1-symmetric sulfoximines have been used as chiral ligands in copper-catalyzed asymmetric hetero Diels-Alder reactions leading to cycloadducts with up to 96% ee.

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Bibliographic Details
Published inChemical communications (Cambridge, England) no. 22; pp. 2826 - 2827
Main Authors Bolm, C, Verrucci, M, Simic, O, Cozzi, PG, Raabe, G, Okamura, H
Format Journal Article
LanguageEnglish
Published CAMBRIDGE Royal Soc Chemistry 01.01.2003
Subjects
Chemistry
Chemistry, Multidisciplinary
Physical Sciences
Science & Technology
SULFOXIMINES
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Summary:Quinoline-based C-1-symmetric sulfoximines have been used as chiral ligands in copper-catalyzed asymmetric hetero Diels-Alder reactions leading to cycloadducts with up to 96% ee.
ISSN:1359-7345
1364-548X
DOI:10.1039/b309556h