Cover Feature: One‐Pot Synthesis of Helical Azaheptalene and Chiroptical Switching of an Isolable Radical Cation (Chem. Eur. J. 48/2023)

In a ballet studio, azaheptalene with M helicity is dancing in front of a mirror. The molecule reflected in the mirror shows a novel azaheptalene with opposite P helicity, and the large torsion angle is described by the dynamic jumping molecule. Its attractive and stimuli‐responsive properties are e...

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Bibliographic Details
Published inChemistry : a European journal Vol. 29; no. 48
Main Authors Nishimura, Yuta, Harimoto, Takashi, Suzuki, Takanori, Ishigaki, Yusuke
Format Journal Article
LanguageEnglish
Published Weinheim Wiley Subscription Services, Inc 25.08.2023
Subjects
azaheptalene
cations
Chemistry
chiroptical response
Helicity
radicals
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Summary:In a ballet studio, azaheptalene with M helicity is dancing in front of a mirror. The molecule reflected in the mirror shows a novel azaheptalene with opposite P helicity, and the large torsion angle is described by the dynamic jumping molecule. Its attractive and stimuli‐responsive properties are expressed rhythmically. This cover implies that the azaheptalene is now ready to come under the big spotlight. More information can be found in the Research Article by Y. Ishigaki and co‐workers (DOI: 10.1002/chem.202301759).
ISSN:0947-6539
1521-3765
DOI:10.1002/chem.202302309