Back Cover: Multiple Triplet Metal‐Centered Jahn‐Teller Isomers Determine Temperature‐Dependent Luminescence Lifetimes in [Ru(bpy)3]2+ (Angew. Chem. Int. Ed. 48/2023)

Calculating temperature‐dependent emission lifetimes is like a scavenger hunt. In their Research Article (e202308803), Leticia González et al. show that in [Ru(bpy)3]2+, the pathway governed by the lowest 3MC‐trans excited state triplet minimum leads astray. Instead, through the concept of rate‐dete...

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Bibliographic Details
Published inAngewandte Chemie International Edition Vol. 62; no. 48
Main Authors Hernández‐Castillo, David, Nau, Roland E. P., Schmid, Marie‐Ann, Tschierlei, Stefanie, Rau, Sven, González, Leticia
Format Journal Article
LanguageEnglish
Published Weinheim Wiley Subscription Services, Inc 27.11.2023
EditionInternational ed. in English
Subjects
Coordination chemistry
Emission lifetimes
Isomers
Jahn-Teller effect
Photophysics
Ruthenium compounds
Temperature dependence
Temperature-dependent photoluminescence
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Summary:Calculating temperature‐dependent emission lifetimes is like a scavenger hunt. In their Research Article (e202308803), Leticia González et al. show that in [Ru(bpy)3]2+, the pathway governed by the lowest 3MC‐trans excited state triplet minimum leads astray. Instead, through the concept of rate‐determining states and an extended kinetic model that takes all the different Jahn–Teller isomers into account, excellent agreement with the experiment is attained.
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.202315666