Frontispiece: The Difference Se Makes: A Bio‐Inspired Dppf‐Supported Nickel Selenolate Complex Boosts Dihydrogen Evolution with High Oxygen Tolerance

Inspiration for the artwork is from the well‐known game “Street Fighter.” In this picture, the bars at the top represent the catalytic H2 evolution turnover frequency (TOF) value of nickel selenolate and nickel sulfur complex (7838 vs 600 s−1). The bars at the bottom represent the determined overpot...

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Published inChemistry : a European journal Vol. 24; no. 33
Main Authors Pan, Zhong‐Hua, Tao, Yun‐Wen, He, Quan‐Feng, Wu, Qiao‐Yu, Cheng, Li‐Ping, Wei, Zhan‐Hua, Wu, Ji‐Huai, Lin, Jin‐Qing, Sun, Di, Zhang, Qi‐Chun, Tian, Dan, Luo, Geng‐Geng
Format Journal Article
LanguageEnglish
Published Weinheim Wiley Subscription Services, Inc 12.06.2018
Subjects
Catalysis
Chemistry
Colleges & universities
DFT calculations
dihydrogen evolution
Flashing
Hydrogen evolution
Lightning
molecular catalysis
Nickel
nickel(II) complexes
oxygen tolerance
Sulfur
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Summary:Inspiration for the artwork is from the well‐known game “Street Fighter.” In this picture, the bars at the top represent the catalytic H2 evolution turnover frequency (TOF) value of nickel selenolate and nickel sulfur complex (7838 vs 600 s−1). The bars at the bottom represent the determined overpotential value of the two nickel complexes (588 vs 544 mV). The flashing lightning and O2 indicate the electrocatalysis carried out under the atmosphere of air. The background picture is one scenic spot, called Cheng Lu Spring, which is located in the Quanzhou campus of Huaqiao University. For more information, see the Communication by G.‐G. Luo et al. on page 8275 ff.
Bibliography:These authors contributed equally to this work.
ISSN:0947-6539
1521-3765
DOI:10.1002/chem.201883364