Frontispiece: Role of Association in Chiral Catalysis: From Asymmetric Synthesis to Spin Selectivity

Spin selectivity, which results in the difference between the chemically induced dynamic nuclear polarisation enhancement coefficients of dyad diastereomers, is a phenomenon observed for chiral systems. This Minireview discusses the chemical nature of spin selectivity and the role of chiral associat...

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Bibliographic Details
Published inChemistry : a European journal Vol. 24; no. 70
Main Authors Ageeva, Aleksandra A., Khramtsova, Ekaterina A., Magin, Ilya M., Purtov, Peter A., Miranda, Miguel A., Leshina, Tatyana V.
Format Journal Article
LanguageEnglish
Published Weinheim Wiley Subscription Services, Inc 12.12.2018
Subjects
asymmetric catalysis
Asymmetric synthesis
Catalysis
Chemical synthesis
Chemistry
chirality
Electron transfer
enantioselectivity
Organic chemistry
Selectivity
spin selectivity
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Summary:Spin selectivity, which results in the difference between the chemically induced dynamic nuclear polarisation enhancement coefficients of dyad diastereomers, is a phenomenon observed for chiral systems. This Minireview discusses the chemical nature of spin selectivity and the role of chiral associates in the chiral catalysis of an elementary radical reaction: electron transfer in chiral dyads. For more information, see the Minireview by Ageeva et al. on page 18587 ff.
ISSN:0947-6539
1521-3765
DOI:10.1002/chem.201887063