ChemInform Abstract: Copper-Catalyzed Decarboxylative Coupling of Alkynyl Carboxylates with 1,1-Dibromo-1-alkenes

This method tolerates a variety of functional groups and yields unsymmetrically substituted 1,3‐diynes or 1,3,5‐triynes with aryl and/or alkyl substituents.

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Bibliographic Details
Published inChemInform Vol. 44; no. 34; p. no
Main Authors Huang, Zheng, Shang, Rui, Zhang, Zi-Rong, Tan, Xiao-Dan, Xiao, Xiao, Fu, Yao
Format Journal Article
LanguageEnglish
Published Weinheim WILEY-VCH Verlag 20.08.2013
WILEY‐VCH Verlag
Wiley Subscription Services, Inc
Subjects
alkynes (acyclic compounds)
alkynes (benzene compounds)
C-C bond formation
catalysis
catalysis, phase‐transfer catalysis
decarboxylation
phase-transfer catalysis
polyphenylalkyne derivatives (tolan derivatives)
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Summary:This method tolerates a variety of functional groups and yields unsymmetrically substituted 1,3‐diynes or 1,3,5‐triynes with aryl and/or alkyl substituents.
Bibliography:ark:/67375/WNG-MCGF07NK-K
ArticleID:CHIN201334079
istex:71A9E0BBF925281FCE9919A228B613450C60258F
ISSN:0931-7597
1522-2667
DOI:10.1002/chin.201334079