ChemInform Abstract: Modular Functionalization of Allenes to Aminated Stereotriads

Rhodium‐catalyzed cyclization of allenic sulfamate (I) provides access towards a strained bicyclic methylene aziridine intermediate, which undergoes aziridine ring opening on reaction with various nucleophiles to afford cyclic sulfamates (III).

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Bibliographic Details
Published inChemInform Vol. 43; no. 51; p. no
Main Authors Adams, Christopher S., Boralsky, Luke A., Guzei, Ilia A., Schomaker, Jennifer M.
Format Journal Article
LanguageEnglish
Published Weinheim WILEY-VCH Verlag 18.12.2012
WILEY‐VCH Verlag
Wiley Subscription Services, Inc
Subjects
diastereoselective syntheses
diastereoselective syntheses, enantioselective syntheses (incl. cis/trans‐isomerism)
enantioselective syntheses (incl. cis/trans-isomerism)
multi-membered O
multi‐membered O,N,S‐heterocycles (with at least 2 different heteroatoms)
S-heterocycles (with at least 2 different heteroatoms)
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Summary:Rhodium‐catalyzed cyclization of allenic sulfamate (I) provides access towards a strained bicyclic methylene aziridine intermediate, which undergoes aziridine ring opening on reaction with various nucleophiles to afford cyclic sulfamates (III).
Bibliography:istex:424085FA9C5040BFECBA3A4D5894CB06D5883475
ark:/67375/WNG-KLDV1MS4-V
ArticleID:CHIN201251149
ISSN:0931-7597
1522-2667
DOI:10.1002/chin.201251149