ChemInform Abstract: In situ Generation of the Ohira-Bestmann Reagent from Stable Sulfonyl Azide: Scalable Synthesis of Alkynes from Aldehydes

An improved method for the in situ generation of the Ohira—Bestmann reagent and its application for a scalable and convenient approach for the synthesis of alkynes from aldehydes is given.

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Bibliographic Details
Published inChemInform Vol. 46; no. 12; p. no
Main Authors Jepsen, Tue Heesgaard, Kristensen, Jesper Langgaard
Format Journal Article
LanguageEnglish
Published Weinheim WILEY-VCH Verlag 01.03.2015
WILEY‐VCH Verlag
Wiley Subscription Services, Inc
Subjects
alkynes (acyclic compounds)
alkynes (benzene compounds)
Azide
C-C bond formation
intermediates (and their reactions)
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Summary:An improved method for the in situ generation of the Ohira—Bestmann reagent and its application for a scalable and convenient approach for the synthesis of alkynes from aldehydes is given.
Bibliography:ark:/67375/WNG-ZWM6H73R-4
istex:4940DED1CD489BA0E76B9AD04BF8DAB4708A758C
ArticleID:CHIN201512099
ISSN:0931-7597
1522-2667
DOI:10.1002/chin.201512099