ChemInform Abstract: Grignard Allylic Substitution Reaction Catalyzed by 1,2,3-Triazol-5-ylidene Magnesium Complexes

The title complexes, generated in situ, efficiently catalyze the substitution reaction of allylic and propargylic compounds with Grignard reagents.

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Bibliographic Details
Published inChemInform Vol. 44; no. 25; p. no
Main Authors Nomura, Ryosuke, Tsuchiya, Yuji, Ishikawa, Hiroyuki, Okamoto, Sentaro
Format Journal Article
LanguageEnglish
Published Weinheim WILEY-VCH Verlag 18.06.2013
WILEY‐VCH Verlag
Wiley Subscription Services, Inc
Subjects
alkenes (acyclic compounds)
alkenes (benzene compounds)
e/z-selectivity (incl. e/z-isomerism)
Magnesium
reactions of organo-metal compounds
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Summary:The title complexes, generated in situ, efficiently catalyze the substitution reaction of allylic and propargylic compounds with Grignard reagents.
Bibliography:istex:8148C5C76A0C3C8F1D600ADAD95E0714FEB628B0
ArticleID:CHIN201325039
ark:/67375/WNG-XZL6SBMF-3
ISSN:0931-7597
1522-2667
DOI:10.1002/chin.201325039