ChemInform Abstract: Copper-Catalyzed Regio- and Stereoselective Intermolecular Three-Component Oxyarylation of Allenes

The Cu‐catalyzed three‐component reaction of allenes, arylboronic acids, and TEMPO is proposed to proceed through carbocupration of allenes, homolysis of the allylcoper(II) intermediate, and final radical TEMPO trapping.

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Bibliographic Details
Published inChemInform Vol. 45; no. 43; p. no
Main Authors Itoh, Taisuke, Shimizu, Yohei, Kanai, Motomu
Format Journal Article
LanguageEnglish
Published Weinheim WILEY-VCH Verlag 21.10.2014
WILEY‐VCH Verlag
Wiley Subscription Services, Inc
Subjects
catalysis
catalysis, phase‐transfer catalysis
multicomponent reactions
phase-transfer catalysis
polyphenylalkene derivatives (stilbene derivatives)
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Summary:The Cu‐catalyzed three‐component reaction of allenes, arylboronic acids, and TEMPO is proposed to proceed through carbocupration of allenes, homolysis of the allylcoper(II) intermediate, and final radical TEMPO trapping.
Bibliography:ArticleID:CHIN201443077
ark:/67375/WNG-ZJKKSVHF-K
istex:A89BE441AD06C840AF81DC455486E66518F8C0E4
ISSN:0931-7597
1522-2667
DOI:10.1002/chin.201443077