ChemInform Abstract: Stereocontrol in Palladium-Catalyzed Propargylic Substitutions: Kinetic Resolution to Give Enantioenriched 1,5-Enynes and Propargyl Acetates

Kinetic resolution during the catalytic allyl‐propargyl cross‐coupling with chiral starting materials can be accomplished with a chiral palladium catalyst.

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Bibliographic Details
Published inChemInform Vol. 45; no. 16; p. no
Main Authors Ardolino, Michael J., Eno, Meredith S., Morken, James P.
Format Journal Article
LanguageEnglish
Published Weinheim WILEY-VCH Verlag 22.04.2014
WILEY‐VCH Verlag
Wiley Subscription Services, Inc
Subjects
C-C bond formation
catalysis
catalysis, phase‐transfer catalysis
diastereoselective syntheses
diastereoselective syntheses, enantioselective syntheses (incl. cis/trans‐isomerism)
enantioselective syntheses (incl. cis/trans-isomerism)
optical resolution
phase-transfer catalysis
stereochemistry (general
stereochemistry (general, optical resolution)
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Summary:Kinetic resolution during the catalytic allyl‐propargyl cross‐coupling with chiral starting materials can be accomplished with a chiral palladium catalyst.
Bibliography:ark:/67375/WNG-5C3LK5DL-9
ArticleID:CHIN201416035
istex:8FD8892F4AD1332A8ADFB8FFBC5F15D8AE656005
ISSN:0931-7597
1522-2667
DOI:10.1002/chin.201416035