ChemInform Abstract: Intramolecular [3 + 2]-Cycloadditions of Azomethine Ylides Derived from Secondary Amines via Redox-Neutral C-H Functionalization

A vast number of secondary amines such as tetrahydroquinoline, tryptoline, pyrrolidine, azepane, morpholine, dihydroindole, and dihydropyrrole derivatives are condensed with azomethine ylides deriving from aldehydes bearing a pendant dipolarophile.

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Bibliographic Details
Published inChemInform Vol. 46; no. 18; p. no
Main Authors Mantelingu, Kempegowda, Lin, Yingfu, Seidel, Daniel
Format Journal Article
LanguageEnglish
Published Weinheim WILEY-VCH Verlag 01.05.2015
WILEY‐VCH Verlag
Wiley Subscription Services, Inc
Subjects
cycloaddition reactions
diastereoselective syntheses
diastereoselective syntheses, enantioselective syntheses (incl. cis/trans‐isomerism)
enantioselective syntheses (incl. cis/trans-isomerism)
fused pyridine derivatives
fused pyrrole derivatives
regioselective reactions
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Summary:A vast number of secondary amines such as tetrahydroquinoline, tryptoline, pyrrolidine, azepane, morpholine, dihydroindole, and dihydropyrrole derivatives are condensed with azomethine ylides deriving from aldehydes bearing a pendant dipolarophile.
Bibliography:ArticleID:CHIN201518215
ark:/67375/WNG-11P5RVTF-D
istex:2B0CF011E8F3764762D14841F0611AE0CD0A4D39
ISSN:0931-7597
1522-2667
DOI:10.1002/chin.201518215