ChemInform Abstract: A Catalytic Enantioselective Tandem Allylation Strategy for Rapid Terpene Construction: Application to the Synthesis of Pumilaside Aglycon

Catalytic diboration of dienes followed by cascade allylborations with dicarbonyl compounds opens access towards terpenoid cyclohexane derivatives.

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Bibliographic Details
Published inChemInform Vol. 44; no. 30; p. no
Main Authors Ferris, Grace E., Hong, Kai, Roundtree, Ian A., Morken, James P.
Format Journal Article
LanguageEnglish
Published Weinheim WILEY-VCH Verlag 23.07.2013
WILEY‐VCH Verlag
Wiley Subscription Services, Inc
Subjects
cyclohexane derivatives
diastereoselective syntheses
diastereoselective syntheses, enantioselective syntheses (incl. cis/trans‐isomerism)
enantioselective syntheses (incl. cis/trans-isomerism)
ring closure reactions
terpenes
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Summary:Catalytic diboration of dienes followed by cascade allylborations with dicarbonyl compounds opens access towards terpenoid cyclohexane derivatives.
Bibliography:ark:/67375/WNG-CNVH872R-1
ArticleID:CHIN201330064
istex:808AC2BBD47DDC7C4E6B573D24420691447DEF20
ISSN:0931-7597
1522-2667
DOI:10.1002/chin.201330064