ChemInform Abstract: Oxidative Transformation of Azides to Aryl Nitriles Using DIB/TBHP: Scope and Mechanistic Insights

Bis(tbutylperoxy)iodobenzene, generated in situ by the reaction between diacetoxyl iodobenzene and tBuOOH, is used in the oxidative transformation of primary azides (I) and (III) to nitriles (II) and (IV).

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Bibliographic Details
Published inChemInform Vol. 43; no. 48; p. no
Main Authors Zhao, Yi, Chew, Xinying, Leung, Gulice Y. C., Yeung, Ying-Yeung
Format Journal Article
LanguageEnglish
Published Weinheim WILEY-VCH Verlag 27.11.2012
WILEY‐VCH Verlag
Wiley Subscription Services, Inc
Subjects
cyanation
cyanation, nitrile formation
nitrile formation
nitriles (benzene compounds)
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Summary:Bis(tbutylperoxy)iodobenzene, generated in situ by the reaction between diacetoxyl iodobenzene and tBuOOH, is used in the oxidative transformation of primary azides (I) and (III) to nitriles (II) and (IV).
Bibliography:ArticleID:CHIN201248063
istex:6DAAECC8D299D93817D89B6C3AE8E0EBA19AD3A0
ark:/67375/WNG-DH347SCR-T
ISSN:0931-7597
1522-2667
DOI:10.1002/chin.201248063