ChemInform Abstract: Synthesis of Cyclic Alkenylsiloxanes by Semihydrogenation: A Stereospecific Route to (Z)-Alkenyl Polyenes

The general route to cyclic alkenylsiloxanes, based on the Lindlar hydrogenation of alkynylsilanes, solves a long‐standing selectivity issue in alkynylsilane reduction chemistry.

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Bibliographic Details
Published inChemInform Vol. 46; no. 4; p. no
Main Authors Elbert, Bryony L., Lim, Diane S. W., Gudmundsson, Haraldur G., O'Hanlon, Jack A., Anderson, Edward A.
Format Journal Article
LanguageEnglish
Published Weinheim WILEY-VCH Verlag 01.01.2015
WILEY‐VCH Verlag
Wiley Subscription Services, Inc
Subjects
alkenes (acyclic compounds)
annulation reactions
e/z-selectivity (incl. e/z-isomerism)
olefination
organo-silicon compounds
ring closure reactions
ring closure reactions, annulation reactions
ring opening reactions
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Summary:The general route to cyclic alkenylsiloxanes, based on the Lindlar hydrogenation of alkynylsilanes, solves a long‐standing selectivity issue in alkynylsilane reduction chemistry.
Bibliography:ark:/67375/WNG-9K53ZSR4-B
istex:90B67094B6C583904DDD5D4A61E43EFC241C653B
ArticleID:CHIN201504053
ISSN:0931-7597
1522-2667
DOI:10.1002/chin.201504053