ChemInform Abstract: A Stereoselective Approach to (Z)-1-Silyl-2-aryl-1,3-dienes from 4-(Phenylselanyl)but-1-yne via Palladium-Catalyzed Silylstannylation and Selenoxide Elimination

The regio‐ and stereoselective silylstannylation of butyne derivative (I) provides the intermediate (III) which is easily converted into the desired products (VI) by combination of oxidative deselenation and Stille cross‐coupling.

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Bibliographic Details
Published inChemInform Vol. 44; no. 21; p. no
Main Authors Shintaku, Kazuki, Maeda, Hajime, Segi, Masahito
Format Journal Article
LanguageEnglish
Published Weinheim WILEY-VCH Verlag 21.05.2013
WILEY‐VCH Verlag
Wiley Subscription Services, Inc
Subjects
alkenes (benzene compounds)
e/z-selectivity (incl. e/z-isomerism)
organo-selenium compounds
organo-silicon compounds
organo-tin compounds
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Summary:The regio‐ and stereoselective silylstannylation of butyne derivative (I) provides the intermediate (III) which is easily converted into the desired products (VI) by combination of oxidative deselenation and Stille cross‐coupling.
Bibliography:istex:A00D7A5D27A632C7308AEA7AEF407DE0F2E6CC86
ArticleID:CHIN201321202
ark:/67375/WNG-HSLMHLPQ-C
ISSN:0931-7597
1522-2667
DOI:10.1002/chin.201321202