ChemInform Abstract: Catalytic Asymmetric Inverse-Electron-Demand Oxa-Diels-Alder Reaction of in situ Generated ortho-Quinone Methides with 3-Methyl-2-vinylindoles

The first examples of an asymmetric inverse‐electron demand oxa‐Diels—Alder reaction of ortho‐quinone methides, generated in situ from ortho‐hydroxybenzyl alcohols, is described using 3‐methyl‐2‐vinylindoles as dienophiles.

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Bibliographic Details
Published inChemInform Vol. 46; no. 36; p. no
Main Authors Zhao, Jia-Jia, Sun, Si-Bing, He, Sai-Huan, Wu, Qiong, Shi, Feng
Format Journal Article
LanguageEnglish
Published Weinheim WILEY-VCH Verlag 01.09.2015
WILEY‐VCH Verlag
Wiley Subscription Services, Inc
Subjects
benzopyran derivatives
cycloaddition reactions
diastereoselective syntheses
diastereoselective syntheses, enantioselective syntheses (incl. cis/trans‐isomerism)
enantioselective syntheses (incl. cis/trans-isomerism)
organocatalysis
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Summary:The first examples of an asymmetric inverse‐electron demand oxa‐Diels—Alder reaction of ortho‐quinone methides, generated in situ from ortho‐hydroxybenzyl alcohols, is described using 3‐methyl‐2‐vinylindoles as dienophiles.
Bibliography:ark:/67375/WNG-X35P79NK-G
istex:11A02DDC4B52CB8C7205B0F6C83E853844003F57
ArticleID:CHIN201536172
ISSN:0931-7597
1522-2667
DOI:10.1002/chin.201536172