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The conversion of readily synthesized α,β‐unsaturated diazoketones to β,γ‐unsaturated amides by a photochemical Wolff rearrangement in the presence of primary and secondary amines is presented.

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Bibliographic Details
Published inChemInform Vol. 45; no. 41; p. no
Main Authors Bernardim, Barbara, Burtoloso, Antonio C. B.
Format Journal Article
LanguageEnglish
Published Weinheim WILEY-VCH Verlag 07.10.2014
WILEY‐VCH Verlag
Wiley Subscription Services, Inc
Subjects
amide formation
Beta
carboxylic amides (acyclic compounds)
chemoluminescence
photochemistry
photochemistry, radiation chemistry, chemoluminescence
radiation chemistry
rearrangements
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Summary:The conversion of readily synthesized α,β‐unsaturated diazoketones to β,γ‐unsaturated amides by a photochemical Wolff rearrangement in the presence of primary and secondary amines is presented.
Bibliography:istex:CB3585120EC038DEC879181B23152FD684048759
ark:/67375/WNG-62TX6PFF-6
ArticleID:CHIN201441061
ISSN:0931-7597
1522-2667
DOI:10.1002/chin.201441061