ChemInform Abstract: Hydrothermal Synthesis, Structure Investigation, and Oxide Ion Conductivity of Mixed Si/Ge-Based Apatite-Type Phases

Mixed Si/Ge‐based single phase apatites ([AI4][AII6] [(BO4)6]O2) of the formula La9.33□0.67Si6‐xGex O26 (□: vacancy; 0 ≤ x ≤ 6) are prepared by mild hydrothermal synthesis from La2O3/(SiO2 + GeO2)/Na2O/H2O gels (autoclave, 180—240 °C).

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Bibliographic Details
Published inChemInform Vol. 45; no. 29; p. no
Main Authors Li, Henan, Baikie, Tom, Pramana, Stevin S., Shin, J. Felix, Keenan, Philip J., Slater, Peter R., Brink, Frank, Hester, James, An, Tao, White, Tim J.
Format Journal Article
LanguageEnglish
Published Weinheim WILEY-VCH Verlag 22.07.2014
WILEY‐VCH Verlag
Wiley Subscription Services, Inc
Subjects
germanium
germanium, Ge
hydrogen
hydrogen, H
lanthanum
lanthanum, La
oxygen
oxygen, O
silicon
silicon, Si
structure (solids and liquids)
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Summary:Mixed Si/Ge‐based single phase apatites ([AI4][AII6] [(BO4)6]O2) of the formula La9.33□0.67Si6‐xGex O26 (□: vacancy; 0 ≤ x ≤ 6) are prepared by mild hydrothermal synthesis from La2O3/(SiO2 + GeO2)/Na2O/H2O gels (autoclave, 180—240 °C).
Bibliography:istex:5C9307F0552B5CF96629AB5C84D767671DA982C0
ArticleID:CHIN201429021
ark:/67375/WNG-HN7HL1DD-X
ISSN:0931-7597
1522-2667
DOI:10.1002/chin.201429021