ChemInform Abstract: First Tandem Asymmetric Conjugate Addition of Alkenyl Nucleophiles and Silyl Trapping of the Intermediate Enolates

The asymmetric Rh‐catalyzed addition of alkenylzirconocenes is described.

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Bibliographic Details
Published inChemInform Vol. 45; no. 14; p. no
Main Authors Westmeier, Johannes, Pfaff, Christopher, Siewert, Juergen, von Zezschwitz, Paultheo
Format Journal Article
LanguageEnglish
Published Weinheim WILEY-VCH Verlag 08.04.2014
WILEY‐VCH Verlag
Wiley Subscription Services, Inc
Subjects
cyclohexane derivatives
cyclopentane derivatives
diastereoselective syntheses
diastereoselective syntheses, enantioselective syntheses (incl. cis/trans‐isomerism)
enantioselective syntheses (incl. cis/trans-isomerism)
multicomponent reactions
reactions of organo-metal compounds
rings with 7 or more members
Trapping
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Summary:The asymmetric Rh‐catalyzed addition of alkenylzirconocenes is described.
Bibliography:ark:/67375/WNG-SBG83P5C-V
istex:598B5A95CD0CE6C46A7CAAC74DA406F54812B9A4
ArticleID:CHIN201414060
ISSN:0931-7597
1522-2667
DOI:10.1002/chin.201414060