1H, 13 and 195Pt NMR studies of some platinumcyclopropane compounds

The 1H, 13C and 195Pt NMR spectral parameters of some platinum—cyclopropane complexes are reported. The NMR parameters, particularly the 13CH coupling constants, suggest the presence of a PtCH 2CH 2C H 2 ring in these compounds. However, there is probably some interaction between platinum and the β-...

Full description

Saved in:
Bibliographic Details
Published inJournal of organometallic chemistry Vol. 71; no. 1; pp. 145 - 151
Main Authors Hall, P.W., Puddephatt, R.J., Tipper, C.F.H.
Format Journal Article
LanguageEnglish
Published Elsevier B.V 01.05.1974
Online AccessGet full text

Cover

More Information
Summary:The 1H, 13C and 195Pt NMR spectral parameters of some platinum—cyclopropane complexes are reported. The NMR parameters, particularly the 13CH coupling constants, suggest the presence of a PtCH 2CH 2C H 2 ring in these compounds. However, there is probably some interaction between platinum and the β-carbon atom acioss the 4-membered ring.
ISSN:0022-328X
1872-8561
DOI:10.1016/S0022-328X(00)93149-8