[ N -(2-Anilinoethyl)- N ′-(trimethylsilyl)benzenecarboximidamidato-κ 3 N , N ′, N ′′](benzonitrile-κ N )trichloridozirconium(IV)

There are two independent molecules in the asymmetric unit of the title compound, [Zr(C 18 H 24 N 3 Si)Cl 3 (C 7 H 5 N)], which are connected by an N—H...Cl hydrogen bond. The Zr atoms are seven-coordinate and possess a distorted pentagonal–bipyramidal geometry. In the crystal, molecules are connect...

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Bibliographic Details
Published inIUCrData Vol. 2; no. 3; p. x170380
Main Authors Li, Wei, Bai, Shengdi, Su, Feng, Duan, Xine, Liu, Diansheng
Format Journal Article
LanguageEnglish
Published International Union of Crystallography 28.03.2017
Subjects
crystal structure
mixed ligands
mononuclear structure
zirconium complex
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Summary:There are two independent molecules in the asymmetric unit of the title compound, [Zr(C 18 H 24 N 3 Si)Cl 3 (C 7 H 5 N)], which are connected by an N—H...Cl hydrogen bond. The Zr atoms are seven-coordinate and possess a distorted pentagonal–bipyramidal geometry. In the crystal, molecules are connected by N—H...Cl hydrogen bonds, forming ribbons along [010].
ISSN:2414-3146
2414-3146
DOI:10.1107/S2414314617003807