Frontispiece: Fabrication of Holey Graphene: Catalytic Oxidation by Metalloporphyrin‐Based Covalent Organic Framework Immobilized on Highly Ordered Pyrolytic Graphite

Holey graphene sheets were achieved through catalytic oxidation of highly ordered pyrolytic graphite (HOPG). A metalloporphyrin‐based covalent organic framework was used to develop a copy‐print process for facile production of holey graphene sheets. Post‐synthetic introduction of hydrogen peroxide/s...

Full description

Saved in:
Bibliographic Details
Published inChemistry : a European journal Vol. 23; no. 24; pp. np - n/a
Main Authors Seo, Wanji, White, David L., Star, Alexander
Format Journal Article
LanguageEnglish
Published Weinheim Wiley Subscription Services, Inc 27.04.2017
Subjects
Catalysis
Catalysts
Catalytic oxidation
Chemistry
Covalence
covalent organic frameworks
Graphene
Graphite
Hydrogen peroxide
nanopatterning
Oxidation
Pyrolytic graphite
Sheets
surface catalysts
Online AccessGet full text

Cover

More Information
Summary:Holey graphene sheets were achieved through catalytic oxidation of highly ordered pyrolytic graphite (HOPG). A metalloporphyrin‐based covalent organic framework was used to develop a copy‐print process for facile production of holey graphene sheets. Post‐synthetic introduction of hydrogen peroxide/sodium hypochlorite facilitated hole production in HOPG. Subsequent exfoliation yielded holey graphene sheets. This innovative tactic allows for production of holey graphene, sidestepping nanolithography present in other methodologies. For the full story see the Communication by A. Star and colleagues on page 5652 ff.
Bibliography:ObjectType-Article-1
SourceType-Scholarly Journals-1
ObjectType-Feature-2
content type line 23
ISSN:0947-6539
1521-3765
DOI:10.1002/chem.201782462