Oxidative Carbonylation of 2-Propyn-1-ol and 2-Methyl-3-butyn-2-ol in an Oscillatory Mode

The oscillatory modes of oxidative carbonylation reaction of two new substrates—2-methyl-3-butyn-2-ol and 2-propyn-1-ol in homogeneous system PdI2-KI-CO-O2-CH3OH are found. Borders of oscillatory areas are drawn, the basic products of reaction are identified, and probable processes routes are offere...

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Bibliographic Details
Published inOrganic chemistry International Vol. 2012; pp. 1 - 6
Main Author Gorodsky, Sergey Nikolaevich
Format Journal Article
LanguageEnglish
Published Hindawi Publishing Corporation 08.04.2012
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Summary:The oscillatory modes of oxidative carbonylation reaction of two new substrates—2-methyl-3-butyn-2-ol and 2-propyn-1-ol in homogeneous system PdI2-KI-CO-O2-CH3OH are found. Borders of oscillatory areas are drawn, the basic products of reaction are identified, and probable processes routes are offered.
ISSN:2090-200X
2090-2018
DOI:10.1155/2012/819190