Solvent isotope effect on the hydroxide-ion-catalyzed hydration of ketenes in aqueous solution

Five ketenes, phenyl(ethyl)ketene, phenyl)methylthio)ketene, diphenylketene, pentafluorophenylketene, and 1-naphthylketene, were generated flash photolytically and solvent isotope effects (H2O vs. D2O) on their hydroxide-ion-catalyzed hydration in aqueous solution was determined.

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Bibliographic Details
Published inCanadian journal of chemistry Vol. 77; no. 4; pp. 459 - 462
Main Authors Andraos, J., Chiang, Y., Eustace, S.J., Kresge, A.J., Paine, S.W., Popik, V.V., Sung, K.
Format Journal Article
LanguageEnglish
Published Ottawa Canadian Science Publishing NRC Research Press 01.04.1999
Subjects
Acids
Chemistry
Hydration
Hydroxy compounds
Ions
Isotopes
Photolysis
Solvents
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Summary:Five ketenes, phenyl(ethyl)ketene, phenyl)methylthio)ketene, diphenylketene, pentafluorophenylketene, and 1-naphthylketene, were generated flash photolytically and solvent isotope effects (H2O vs. D2O) on their hydroxide-ion-catalyzed hydration in aqueous solution was determined.
ISSN:0008-4042
1480-3291
DOI:10.1139/cjc-77-4-459