ZnO‐activated formation of phase pure perovskite Pb(In 1/2 Nb 1/2 )O 3 ‐Pb(Zn 1/3 Nb 2/3 )O 3 ‐PbTiO 3 powder

• Published in: Journal of the American Ceramic Society Vol. 102; no. 7; pp. 3932 - 3939
• Main Authors: Brova, Michael J., Watson, Beecher H., R. Kupp, Elizabeth, Fanton, Mark A., Meyer, Richard J., Messing, Gary L.
• Format: Journal Article
• Language: English
• Published: 01.07.2019
• ISSN: 0002-7820; 1551-2916
• DOI: 10.1111/jace.16296

Abstract This paper reports on the phase formation of perovskite Pb(In 1/2 Nb 1/2 )O 3 ‐Pb(Zn 1/3 Nb 2/3 )O 3 ‐PbTiO 3 ( PIN ‐ PZN ‐ PT ) powder when doped with 0.04 to 0.83 mol% ZnO. Air calcination of undoped powder mixtures for 4 hours at 800°C resulted in a mixture of Pb 2 Zn 0.29 Nb 1.71 O 6.565 pyrochlore, PIN ‐ PZN ‐ PT perovskite, and In 2 O 3 . ZnO dopant concentrations as low as 0.04 mol% increased the rate of perovskite formation and resulted in near phase pure perovskite powder of 0.5 μm particle size when heated at 800°C in air. In all cases PbTiO 3 and Pb(In 1/2 Nb 1/2 )O 3 formed prior to PIN ‐ PZN ‐ PT formation. ZnO doping promotes perovskite phase formation by increasing the reactivity of the intermediate pyrochlore phase by substituting Zn 2+ on Nb 5+ sites and forming oxygen vacancies when heated in air. Heating in high resulted in an incomplete reaction and a mixture of perovskite and pyrochlore whereas low resulted in phase separation into a mixture of rhombohedral perovskite, tetragonal perovskite, and pyrochlore. The sensitivity clearly shows that oxygen vacancies due to ZnO‐doping are critical for synthesis of phase pure PIN ‐ PZN ‐ PT powder.