Joule heating driven infrared switching in flexible VO 2 nanoparticle films with reduced energy consumption for smart windows

• Published in: Journal of materials chemistry. A, Materials for energy and sustainability Vol. 7; no. 9; pp. 4516 - 4524
• Main Authors: Shen, Nan, Chen, Shi, Wang, Weijun, Shi, Run, Chen, Pengcheng, Kong, Dejun, Liang, Yuxing, Amini, Abbas, Wang, Jianbo, Cheng, Chun
• Format: Journal Article
• Language: English
• Published: 26.02.2019
• ISSN: 2050-7488; 2050-7496
• DOI: 10.1039/C8TA11071A

Vanadium dioxide (VO 2 ) is emerging as the most promising candidate for next-generation smart windows. However, the applications of VO 2 -based films encounter the bottleneck of its optimal thermochromic property being unable to be retained as the modulating phase transition temperature approaches the ambient temperature. Joule heating is an effective approach to maintain the infrared switching ability of pristine VO 2 films, but the accompanied energy consumption and its effects on the infrared switching ability of flexible VO 2 films are still unexplored. Here, we fabricated flexible VO 2 nanoparticle films via a scalable blade-coating process and investigated the effects of Joule heating on the infrared switching of flexible VO 2 films. Infrared switching triggered by Joule heating can be effectively managed by the input voltages with high stability and exhibited no obvious degradation even after 10 000 bending cycles, suggesting excellent flexibility. Importantly, we found that maximum infrared switching ability could be sustained with a dramatically reduced power, 15% of the threshold power (224 mW cm −2 ), by utilizing the hysteresis behaviour of the as-prepared VO 2 films. This study provides a practical strategy for utilizing hysteresis behaviour to maintain the optimal infrared switching ability of flexible VO 2 films with low energy consumption, substantially promoting the development of flexible smart devices.