Natrium-bis [trimethylsilyl] -amid als Protonenacceptor gegenüber organischen Liganden in substituierten Metallcarbonylen

The reaction of M(CO) NCCH (M = Cr, Mo, W) and C Fe(CO)3 with sodium bis-[trimethylsilyl] amide does not lead to the transformation of a CO group into CN⁻, but instead, to a deprotonation to give the anions [M(CO) NCCH ]⁻ and [C Fe(CO) ]⁻.

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Bibliographic Details
Published inZeitschrift für Naturforschung. B, A journal of chemical sciences Vol. 31; no. 8; pp. 1019 - 1020
Main Authors Moll, Matthias, Behrens, Helmut, Kellner, Reinhard, Knöchel, Hans, Würstl, Peter
Format Journal Article
LanguageEnglish
Published Verlag der Zeitschrift für Naturforschung 01.08.1976
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Summary:The reaction of M(CO) NCCH (M = Cr, Mo, W) and C Fe(CO)3 with sodium bis-[trimethylsilyl] amide does not lead to the transformation of a CO group into CN⁻, but instead, to a deprotonation to give the anions [M(CO) NCCH ]⁻ and [C Fe(CO) ]⁻.
ISSN:0932-0776
1865-7117
DOI:10.1515/znb-1976-0802