XRD and EXAFS study of nitrato ammine complexes of nitrosyl ruthenium

The structure of trans -[RuNO(NH 3 ) 4 (H 2 O)](NO 3 ) 3 ( I ) and trans -[RuNO(NH 3 ) 4 (NO 3 )](NO 3 ) 2 ( II ) was determined by XRD. Crystallographic data are as follows: space group I 4 1 / a ; a = b = 18.280(1) Å, c = 15.129(1) Å, R = 0.0244 ( I ), and space group Cm , a = 11.5620(3) Å, b = 7....

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Published inJournal of structural chemistry Vol. 51; no. Suppl 1; pp. 73 - 80
Main Authors Kabin, E. V., Emel’yanov, V. A., Baidina, I. A., Nedoseykina, T. I., Vorob’yov, V. A.
Format Journal Article
LanguageEnglish
Published Dordrecht SP MAIK Nauka/Interperiodica 01.12.2010
Subjects
Atomic
Atomic/Molecular Structure and Spectra
Chemistry
Chemistry and Materials Science
Inorganic Chemistry
Molecular
Optical and Plasma Physics
Physical Chemistry
Solid State Physics
ruthenium
ammine complexes
X-ray diffraction analysis
EXAFS
nitrosyl complexes
nitrato complexes
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Summary:The structure of trans -[RuNO(NH 3 ) 4 (H 2 O)](NO 3 ) 3 ( I ) and trans -[RuNO(NH 3 ) 4 (NO 3 )](NO 3 ) 2 ( II ) was determined by XRD. Crystallographic data are as follows: space group I 4 1 / a ; a = b = 18.280(1) Å, c = 15.129(1) Å, R = 0.0244 ( I ), and space group Cm , a = 11.5620(3) Å, b = 7.9934(2) Å, c = 7.7864(2) Å, β = 127.124(1)°, R = 0.0139 ( II ). Interatomic distances for complex particles of fac - and mer - [RuNO(NH 3 ) 2 (NO 3 ) 3 ] ( III and IV , respectively) were determined by EXAFS.
ISSN:0022-4766
1573-8779
DOI:10.1007/s10947-010-0192-y