6Li and 7Li MAS NMR spectra of complex lyonsite-type Li2Zn2(MoO4)3 and LiRb3Hf2(MoO4)6 lithium molybdates

6 Li and 7 Li MAS NMR spectra of complex Li 2 Zn 2 (MoO 4 ) 3 and LiRb 3 Hf 2 (MoO 4 ) 6 molybdates of lyonsite-type structure are studied at temperatures ranging from 25 to 100°C. NMR signals are attributed to their sources. It is shown that the presence of a transition metal such as Hf in the +4 o...

Full description

Saved in:
Bibliographic Details
Published inBulletin of the Russian Academy of Sciences. Physics Vol. 78; no. 8; pp. 760 - 761
Main Authors Nevmyvako, R. D., Zhuravlev, N. A., Tsyrenova, G. D., Balsanova, L. V., Denisova, T. A., Mikhalev, K. N., Pavlova, E. T.
Format Journal Article
LanguageEnglish
Published Heidelberg Allerton Press 01.08.2014
Subjects
Hadrons
Heavy Ions
Nuclear Physics
Physics
Physics and Astronomy
Proceedings of the International Symposium “Environments with Structural and Magnetic Ordering” Multiferroics 4
Plex Oxide
LiRb
Magic Angle Spin
Mixed Occupation
Molybdate
Online AccessGet full text

Cover

More Information
Summary:6 Li and 7 Li MAS NMR spectra of complex Li 2 Zn 2 (MoO 4 ) 3 and LiRb 3 Hf 2 (MoO 4 ) 6 molybdates of lyonsite-type structure are studied at temperatures ranging from 25 to 100°C. NMR signals are attributed to their sources. It is shown that the presence of a transition metal such as Hf in the +4 oxidation state in the structure of lyonsite contributes to the increased mobility of lithium ions along the channels of the crystal structure.
ISSN:1062-8738
1934-9432
DOI:10.3103/S1062873814080267