A Topotactic Synthetic Methodology for Highly Fluorine-Doped Mesoporous Metal Oxides

F‐Taktik: Hoch fluordotierte mesoporöse Metalloxide (bis 40 Atom‐%) wurden ausgehend von mesoporösen Metalloxiden durch topotaktische Fluorierung mit Fluor hergestellt. Die Oberflächen, Porengröße und ‐volumen sowie die Konzentration der Fluoratome dieser Materialien ließen sich durch Variation der...

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Published inAngewandte Chemie Vol. 124; no. 12; pp. 2942 - 2947
Main Authors Qiao, Zhen-an, Brown, Suree S., Adcock, Jamie, Veith, Gabriel M., Bauer, J. Chris, Payzant, E. Andrew, Unocic, Raymond R., Dai, Sheng
Format Journal Article
LanguageEnglish
Published Weinheim WILEY-VCH Verlag 19.03.2012
WILEY‐VCH Verlag
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Summary:F‐Taktik: Hoch fluordotierte mesoporöse Metalloxide (bis 40 Atom‐%) wurden ausgehend von mesoporösen Metalloxiden durch topotaktische Fluorierung mit Fluor hergestellt. Die Oberflächen, Porengröße und ‐volumen sowie die Konzentration der Fluoratome dieser Materialien ließen sich durch Variation der Fluorierungszeit und ‐temperatur über einen breiten Bereich einstellen.
Bibliography:Office of Basic Energy Sciences, US Department of Energy
istex:8149C2FDA59EAC599F4618BD6A0A5C6524BD073F
ArticleID:ANGE201107812
ark:/67375/WNG-JD197WMB-R
This work was sponsored by the Materials Sciences and Engineering Division (Z.A.Q., J.A., G.M.V., R.R.U., S.D.) and the Division of Chemical Sciences, Geosciences, and Biosciences (S.B., J.C.B.), Office of Basic Energy Sciences, US Department of Energy. A portion of this research was conducted at the Center for Nanophase Materials Sciences, which is sponsored at Oak Ridge National Laboratory by the Office of Basic Energy Sciences, US Department of Energy. Microscopy was supported by ORNL's Shared Research Equipment (SHaRE) User Facility, which is sponsored by the Office of Basic Energy Sciences, US Department of Energy.
This work was sponsored by the Materials Sciences and Engineering Division (Z.A.Q., J.A., G.M.V., R.R.U., S.D.) and the Division of Chemical Sciences, Geosciences, and Biosciences (S.B., J.C.B.), Office of Basic Energy Sciences, US Department of Energy. A portion of this research was conducted at the Center for Nanophase Materials Sciences, which is sponsored at Oak Ridge National Laboratory by the Office of Basic Energy Sciences, US Department of Energy. Microscopy was supported by ORNL’s Shared Research Equipment (SHaRE) User Facility, which is sponsored by the Office of Basic Energy Sciences, US Department of Energy.
ISSN:0044-8249
1521-3757
DOI:10.1002/ange.201107812