STATIC AND DYNAMIC POLARIZABILITIES IN HYPERSENSITIVE TRANSITIONS IN COMPOUNDS Nd (pic) 3 .3 (tmso) AND Nd (pic) 3 .2 (rac-besm) IN ACETONITRILE SOLUTIONS AND NITROMETAN

In this work the electronic polarizability of the Nd3+ ion in the Nd(pic)3.3(tmso) and Nd(pic) 3.2(rac-besm) compounds were appraised in acetonitrile and nitromethane solutions. Then they were compared with the b, d, and b1/2 bonding optical parameters in solution. The program WebLab ViewerPro was a...

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Bibliographic Details
Published inTchê química Vol. 4; no. 2; pp. 31 - 39
Main Authors LIMA, Francisco José Santos, SILVA, Marcos Antônio Andrade da
Format Journal Article
LanguageEnglish
Published 20.08.2005
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Summary:In this work the electronic polarizability of the Nd3+ ion in the Nd(pic)3.3(tmso) and Nd(pic) 3.2(rac-besm) compounds were appraised in acetonitrile and nitromethane solutions. Then they were compared with the b, d, and b1/2 bonding optical parameters in solution. The program WebLab ViewerPro was applied for the construction of the molecular model of these compounds and the obtained experimental data was interpreted. It was observed a strait relationship among the character of the metal-ligand connection, the electronic polarizability and the steric effects, in the studied compounds.
ISSN:1806-0374
1806-0374
DOI:10.52571/PTQ.v2.n04.2005.AGOSTO/2_pgs_31_39.pdf