Front Cover: Dirhodium(II)‐Catalyzed C(sp2)−H Azidation of Benzaldehydes (Chem. Eur. J. 30/2020)

Taming azide radicals for catalytic C(sp2)−H azidation of benzaldehydes: In this manuscript, dirhodium complexes, represented by the classical Chinese lantern structure, reacted with azide radical to form Rh2(II,III)N3, which is responsible for the azide transfer. In the picture, the girl carrying a...

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Bibliographic Details
Published inChemistry : a European journal Vol. 26; no. 30; p. 6736
Main Authors Wang, Yi, Fang, Zaixiang, Chen, Xiaochuan, Wang, Yuanhua
Format Journal Article
LanguageEnglish
Published 26.05.2020
Subjects
aromatic aldehydes
azidation
dirhodium
one-electron oxidation
radicals
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Summary:Taming azide radicals for catalytic C(sp2)−H azidation of benzaldehydes: In this manuscript, dirhodium complexes, represented by the classical Chinese lantern structure, reacted with azide radical to form Rh2(II,III)N3, which is responsible for the azide transfer. In the picture, the girl carrying a lantern illuminates the direction of the paper boats loading the azide radicals, which means the dirhodium complexes direct the free azide radical to the desired reaction pathway. More information can be found in the Full Paper by Y. H. Wang et al. on page 6805.
ISSN:0947-6539
1521-3765
DOI:10.1002/chem.202001172