Tetraphenylphosphonium [2-(mercaptomethylcarbonylamino)- N -(2-methylaminophenyl)ethanamido(4−)-κ 4 S , N , N ′, N ′′]oxorhenate(V)

The title compound, (C 24 H 20 P)[Re(C 11 H 11 N 3 O 2 S)O], is the [(C 6 H 5 ) 4 P] + salt of a square-pyramidal [ReO L ] − complex anion [ L is the deprotonated 2-(mercaptomethylcarbonylamino)- N -(2-methylaminophenyl)ethanamide ligand], in which the Re=O bond is apical and the tetradentate (N—N—N...

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Published inActa crystallographica. Section E, Structure reports online Vol. 63; no. 3; pp. m868 - m869
Main Authors Le Gal, Julien, Benoist, Éric, Gressier, Marie, Bélanger-Gariépy, Francine, Beauchamp, André L.
Format Journal Article
LanguageEnglish
Published 01.03.2007
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Summary:The title compound, (C 24 H 20 P)[Re(C 11 H 11 N 3 O 2 S)O], is the [(C 6 H 5 ) 4 P] + salt of a square-pyramidal [ReO L ] − complex anion [ L is the deprotonated 2-(mercaptomethylcarbonylamino)- N -(2-methylaminophenyl)ethanamide ligand], in which the Re=O bond is apical and the tetradentate (N—N—N—S) 4− ligand fills the four basal sites. The presence of a methyl group on the terminal N-atom donor induces a small displacement of the coordinated S atom.
ISSN:1600-5368
1600-5368
DOI:10.1107/S1600536807008070