ChemInform Abstract: Lithium Acetylides as Alkynylating Reagents for the Enantioselective Alkynylation of Ketones Catalyzed by Lithium Binaphtholate

Optically active propargyl alcohols are synthesized via the enantioselective addition of lithium acetylides to ketones.

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Bibliographic Details
Published inChemInform Vol. 42; no. 37; p. no
Main Authors Tanaka, Kana, Kukita, Kenji, Ichibakase, Tomonori, Kotani, Shunsuke, Nakajima, Makoto
Format Journal Article
LanguageEnglish
Published Weinheim WILEY-VCH Verlag 13.09.2011
WILEY‐VCH Verlag
Subjects
addition reactions
alkynes (benzene compounds)
diastereoselective syntheses
diastereoselective syntheses, enantioselective syntheses (incl. cis/trans‐isomerism)
enantioselective syntheses (incl. cis/trans-isomerism)
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Summary:Optically active propargyl alcohols are synthesized via the enantioselective addition of lithium acetylides to ketones.
Bibliography:istex:CD8942EE2CE0361C854069610A8E5F5065D954B5
ArticleID:CHIN201137029
ark:/67375/WNG-6C9JFGN0-V
ISSN:0931-7597
1522-2667
DOI:10.1002/chin.201137029