ChemInform Abstract: Direct β-Functionalization of Cyclic Ketones with Aryl Ketones via the Merger of Photoredox and Organocatalysis

The reaction proceeds via photoinduced single electron transfers (SET) of the aryl ketones and enamines generated from the cyclic ketones and azepane followed by radical—radical coupling.

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Bibliographic Details
Published inChemInform Vol. 45; no. 24; p. no
Main Authors Petronijevic, Filip R., Nappi, Manuel, MacMillan, David W. C.
Format Journal Article
LanguageEnglish
Published Weinheim WILEY-VCH Verlag 17.06.2014
WILEY‐VCH Verlag
Subjects
alcohols (benzene compounds)
C-C bond formation
chemoluminescence
cycloalkylphenyl derivatives
organocatalysis
photochemistry
photochemistry, radiation chemistry, chemoluminescence
radiation chemistry
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Summary:The reaction proceeds via photoinduced single electron transfers (SET) of the aryl ketones and enamines generated from the cyclic ketones and azepane followed by radical—radical coupling.
Bibliography:istex:9F6F400F2F6AF3329B875D00E69ED8B0D0A59506
ark:/67375/WNG-94S39SFX-3
ArticleID:CHIN201424098
ISSN:0931-7597
1522-2667
DOI:10.1002/chin.201424098