ChemInform Abstract: Asymmetric Synthesis of Highly Functionalized γ-Lactams Through an Organocatalytic aza-Michael-Michael Reaction Cascade Using Fumaric Acid Amide Esters as Multi-Reactive Substrates

The process employs primary and secondary amine organocatalysts allowing the synthesis of mono and bicyclic lactam frameworks.

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Bibliographic Details
Published inChemInform Vol. 43; no. 26; p. no
Main Authors Yokosaka, Takuya, Hamajima, Akinari, Nemoto, Tetsuhiro, Hamada, Yasumasa
Format Journal Article
LanguageEnglish
Published Weinheim WILEY-VCH Verlag 26.06.2012
WILEY‐VCH Verlag
Subjects
diastereoselective syntheses
diastereoselective syntheses, enantioselective syntheses (incl. cis/trans‐isomerism)
enantioselective syntheses (incl. cis/trans-isomerism)
fused pyrrole derivatives
organocatalysis
pyrrole derivatives
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Summary:The process employs primary and secondary amine organocatalysts allowing the synthesis of mono and bicyclic lactam frameworks.
Bibliography:ark:/67375/WNG-D6FBZ3KT-P
istex:B65609FD920D68B846EE7C8492A7E07D706CFBEA
ArticleID:CHIN201226107
ISSN:0931-7597
1522-2667
DOI:10.1002/chin.201226107