Probing with Nuclear Magnetic Resonance echo decay and relaxation: A study on nitrile butadiene rubber

• Published in: Solid state nuclear magnetic resonance Vol. 51-52; pp. 16 - 24
• Main Authors: Sturniolo, Simone, Pieruccini, Marco, Corti, Maurizio, Rigamonti, Attilio
• Format: Journal Article
• Language: English
• Published: 01.05.2013
• Subjects: Butadiene; Computer programs; Correlation; Decay; Echo surveys; Nuclear magnetic resonance; Reconstruction; Software
• ISSN: 0926-2040
• DOI: 10.1016/j.ssnmr.2012.12.001

One dimensional 1H NMR measurements have been performed to probe slow molecular motions in nitrile butadiene rubber (NBR) around its calorimetric glass transition temperature T g . The purpose is to show how software aided data analysis can extract meaningful dynamical data from these measurements. Spinalattice relaxation time, free induction decay (FID) and magic sandwich echo (MSE) measurements have been carried out at different values of the static field, as a function of temperature. It has been evidenced how the efficiency of the MSE signal in reconstructing the original FID exhibits a sudden minimum at a given temperature, with a slight dependence from the measuring frequency. Computer simulations performed with the software SPINEVOLUTION have shown that the minimum in the efficiency reconstruction of the MSE signal corresponds to the average motional frequency taking a value around the inter-proton coupling. The FID signals have been fitted with a truncated form of a newly derived exact correlation function for the transverse magnetization of a dipolar interacting spin pair, which allows one to avoid the restriction of the stationary and Gaussian approximations. A direct estimate of the conformational dynamics on approaching the T g is obtained, and the results are in agreement with the analysis performed via the MSE reconstruction efficiency. The occurrence of a wide distribution of correlation frequencies for the chains motion, with a VogelaFulcher type temperature dependence, is addressed. A route for a fruitful study of the dynamics accompanying the glass transition by a variety of NMR measurements is thus proposed.