ChemInform Abstract: Environmentally Benign Regio- and Stereoselective Synthesis of Functionalized Tertiary Amines

Baylis—Hillman adducts (I) react regio‐ and stereoselectively with various primary aliphatic amines under neat conditions to potentially valuable building blocks containing reactive C—C double bonds and an ester and cyano group, respectively.

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Bibliographic Details
Published inChemInform Vol. 41; no. 48; p. no
Main Authors Wang, Rendong, Li, Jian, Li, Chunju, Liu, Jun, Li, Dafeng, Jia, Xueshun, Zhai, Hongbin
Format Journal Article
LanguageEnglish
Published Weinheim WILEY-VCH Verlag 30.11.2010
WILEY‐VCH Verlag
Subjects
amination
amination, N‐alkylation, N‐arylation
amines (benzene compounds)
e/z-selectivity (incl. e/z-isomerism)
N-alkylation
N-arylation
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Summary:Baylis—Hillman adducts (I) react regio‐ and stereoselectively with various primary aliphatic amines under neat conditions to potentially valuable building blocks containing reactive C—C double bonds and an ester and cyano group, respectively.
Bibliography:istex:7F69526F36AE5F639405DDCAF50FCFC9958CBE6A
ArticleID:CHIN201048056
ark:/67375/WNG-5KT19D20-R
ISSN:0931-7597
1522-2667
DOI:10.1002/chin.201048056