Metal Phosphinylides and Phosphinothioylides. VII. The Structure of [Ph2PX]M (X=O, S) in Solution and Their Disproportionation

The species [Ph2PO]M in THF were found to exist as Ph2P–O–M by 31P-NMR, and [Ph2PS]MgCl as Ph2P–S–MgCl by Raman spectrum. The species [Ph2PS]M undergo easy disproportionation by heating.

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Bibliographic Details
Published inBulletin of the Chemical Society of Japan Vol. 50; no. 2; pp. 545 - 546
Main Authors Goda, Koshiro, Gomi, Hideyuki, Yoshifuji, Masaaki, Inamoto, Naoki
Format Journal Article
LanguageEnglish
Published The Chemical Society of Japan 01.02.1977
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Summary:The species [Ph2PO]M in THF were found to exist as Ph2P–O–M by 31P-NMR, and [Ph2PS]MgCl as Ph2P–S–MgCl by Raman spectrum. The species [Ph2PS]M undergo easy disproportionation by heating.
ISSN:0009-2673
1348-0634
DOI:10.1246/bcsj.50.545