Back Cover: Residual Dipolar Couplings as a Powerful Tool for Constitutional Analysis: The Unexpected Formation of Tricyclic Compounds (Angew. Chem. Int. Ed. 11/2011)

Puzzle solved:Residual dipolar couplings (RDCs) can be a powerful method to determine the constitution of molecules when traditional methods for structure elucidation fail. In their Communication on page 2643 ff., B. Luy, S. F. Kirsch, and co‐workers demonstrate this method with products obtained by...

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Published inAngewandte Chemie International Edition Vol. 50; no. 11; p. 2648
Main Authors Kummerlöwe, Grit, Crone, Benedikt, Kretschmer, Manuel, Kirsch, Stefan F., Luy, Burkhard
Format Journal Article
LanguageEnglish
Published Weinheim WILEY-VCH Verlag 07.03.2011
WILEY‐VCH Verlag
Subjects
electrophiles
enynes
NMR spectroscopy
residual dipolar couplings
structure elucidation
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Summary:Puzzle solved:Residual dipolar couplings (RDCs) can be a powerful method to determine the constitution of molecules when traditional methods for structure elucidation fail. In their Communication on page 2643 ff., B. Luy, S. F. Kirsch, and co‐workers demonstrate this method with products obtained by treating an azide‐containing 1,5‐enyne in the presence of electrophilic iodine sources: whereas standard analytical methods only left an unsolved structural jigsaw puzzle, the use of RDCs allowed the molecules to be identified. The authors thank R. Oehme for his support with the back‐cover design.
Bibliography:ark:/67375/WNG-VFVQT9Q6-7
ArticleID:ANIE201101025
istex:4379CE810E6051F5CF8624C5FDDD920DEC3B2417
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.201101025