ChemInform Abstract: Synthesis in Ionic Liquids only: Access to α-Oxo-γ-thio-esters via Mukaiyama Coupling

Mukaiyama coupling of thioacetals with pyruvate enoxysilane proceeds in ionic liquid to give the desired α‐oxy‐γ‐thioesters in case for substrates (Ia) and (Ib).

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Bibliographic Details
Published inChemInform Vol. 45; no. 29; p. no
Main Authors Jebri, Khouloud, Mazieres, Marie-Rose, Ballereau, Stephanie, Ben Ayed, Taicir, Plaquevent, Jean-Christophe, Baltas, Michel, Guillen, Frederic
Format Journal Article
LanguageEnglish
Published Weinheim WILEY-VCH Verlag 22.07.2014
WILEY‐VCH Verlag
Subjects
carboxylic acid esters (acyclic compounds)
catalysis
catalysis, phase‐transfer catalysis
mercaptans
mercaptans, thioethers (benzene compounds)
phase-transfer catalysis
solvents
thioethers (benzene compounds)
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Summary:Mukaiyama coupling of thioacetals with pyruvate enoxysilane proceeds in ionic liquid to give the desired α‐oxy‐γ‐thioesters in case for substrates (Ia) and (Ib).
Bibliography:istex:FC7EC17FB91E829357D6F3956D7EBDEFA6C9E22B
ark:/67375/WNG-F5BGM0RP-9
ArticleID:CHIN201429064
ISSN:0931-7597
1522-2667
DOI:10.1002/chin.201429064