ChemInform Abstract: Negishi Cross-Coupling of Secondary Alkylzinc Halides with Aryl/Heteroaryl Halides Using Pd-PEPPSI-IPent

The highly‐hindered Ipent ligand significantly reduces the production of isomeric coupling products due to β‐hydride elimination/migratory insertion of the organometallic reagent.

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Bibliographic Details
Published inChemInform Vol. 42; no. 36; p. no
Main Authors Calimsiz, Selcuk, Organ, Michael G.
Format Journal Article
LanguageEnglish
Published Weinheim WILEY-VCH Verlag 06.09.2011
WILEY‐VCH Verlag
Subjects
aldehydes (benzene compounds)
carboxylic acid esters (benzene compounds)
cycloalkylphenyl derivatives
nitriles (benzene compounds)
phenol ethers
pyridazine derivatives
reactions of organo-metal compounds
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Summary:The highly‐hindered Ipent ligand significantly reduces the production of isomeric coupling products due to β‐hydride elimination/migratory insertion of the organometallic reagent.
Bibliography:ark:/67375/WNG-Z58S0F0D-W
ArticleID:CHIN201136043
istex:148DA7315F34CC427ACEAE255F4611691F492226
ISSN:0931-7597
1522-2667
DOI:10.1002/chin.201136043