ChemInform Abstract: Synthesis of α,β-Unsaturated Caprolactams Starting from Heterocyclic Imines

Addition of unsaturated acid chlorides (II) to heterocyclic imines (I) followed by reaction with unsaturated nucleophiles (III), (VI), (IX) and subsequent ring closing metathesis afford the α,β‐unsaturated caprolactams (V), (VIII) and (XI), containing, sulfur, nitrogen, or selenium atoms in the δ‐po...

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Published inChemInform Vol. 41; no. 41; p. no
Main Authors Johannes, Katharina, Watzke, Martin, Martens, Juergen
Format Journal Article
LanguageEnglish
Published Weinheim WILEY-VCH Verlag 12.10.2010
WILEY‐VCH Verlag
Subjects
metathesis reactions
multi-membered N-heterocycles
multi-membered O
multi‐membered O,N,S‐heterocycles (with at least 2 different heteroatoms)
organo-selenium compounds
S-heterocycles (with at least 2 different heteroatoms)
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Summary:Addition of unsaturated acid chlorides (II) to heterocyclic imines (I) followed by reaction with unsaturated nucleophiles (III), (VI), (IX) and subsequent ring closing metathesis afford the α,β‐unsaturated caprolactams (V), (VIII) and (XI), containing, sulfur, nitrogen, or selenium atoms in the δ‐position.
Bibliography:ark:/67375/WNG-0NQPZXQ8-K
istex:901A56006E4605E008D0A214C2D9CB01249797B9
ArticleID:CHIN201041043
ISSN:0931-7597
1522-2667
DOI:10.1002/chin.201041043