ChemInform Abstract: γ-Aminoalcohol Rearrangement Applied to Pentahydroxylated Azepanes Provides Pyrrolidines Epimeric to HomoDMDP

A short sequence is described for the conversion of azepanes (I) and (V) into pyrrolidines (IV) and (VIII), which are epimeric to α‐glucosidase inhibitor homoDMDP.

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Bibliographic Details
Published inChemInform Vol. 46; no. 28; p. no
Main Authors Jagadeesh, Y., Tran, A. T., Luo, B., Auberger, N., Desire, J., Nakagawa, S., Kato, A., Zhang, Y., Sollogoub, M., Bleriot, Y.
Format Journal Article
LanguageEnglish
Published Weinheim WILEY-VCH Verlag 01.07.2015
WILEY‐VCH Verlag
Subjects
pyrrole derivatives
ring contraction
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Summary:A short sequence is described for the conversion of azepanes (I) and (V) into pyrrolidines (IV) and (VIII), which are epimeric to α‐glucosidase inhibitor homoDMDP.
Bibliography:istex:D3B32DBABC9440911DAF1343A6875117A4B786BB
ark:/67375/WNG-8L709W70-H
ArticleID:CHIN201528140
ISSN:0931-7597
1522-2667
DOI:10.1002/chin.201528140