Application of DPG / KH550 modified pyrolysis carbon black in oil and high temperature‐resistant NBR composites

• Published in: Journal of applied polymer science
• Main Authors: Ge, Yaqi, Diao, Pengfei, Li, Xiangxu, Zhou, Yukun, Xu, Zhenchun, Bian, Huiguang, Xiao, Yao, Wang, Chuansheng
• Format: Journal Article
• Language: English
• Published: 08.10.2024
• ISSN: 0021-8995; 1097-4628
• DOI: 10.1002/app.56377

Abstract In this paper, pyrolysis carbon black (CBp) was introduced into nitrile butadiene rubber (NBR), the effects of the ratio of CBp and carbon black (N326) on the properties of NBR composites were investigated, and the optimal ratio was determined. On this basis, the accelerator DPG, coupling agent KH550 and CBp were modified by ball milling and plasma. The results showed that when the ratio of CBp to N326 was 40:15, the overall properties of NBR composites was better. Compared with the unmodified CBp/NBR composites, the change rate of tensile product, resilience and DIN abrasion of ball milling‐plasma modified CBp/NBR composites in oil environment were reduced by 52.96%, 12.81%, and 27.19%, respectively, and the tear strength after double damage by high temperature and oil bath was increased by 15.63%, which resulted in better oil and high temperature‐resistance. In summary, the ball milling‐plasma combined with DPG/KH550 modified CBp can not only replace N326 carbon black, but also realize the preparation of NBR composites with better oil and high temperature‐resistance.